Mister Miracle #1 CGC 9.2 White Pages, 1st appearance Mr. Miracle and Oberon.
Ms. Marvel #1 CGC 9.8 White Pages 1st Carol Danvers as Ms. Marvel.
Ms. Marvel #16 CGC 9.8 White Pages 1st appearance of Mystique in cameo
Shazam! #1 CGC 9.8 White Pages, First Captain Marvel in DC Comics; First appearance since Golden Age; First Sivana Family in DC Comics
Special Marvel Edition #16 - 1974, First appearance of Midnight
Strange Tales #135 CGC 9.0 1st appearance Nick Fury & Agents of S.H.I.E.L.D., & Hydra, SIGNED BY STAN LEE
Strange Tales #138 CGC 9.4 1st appearance of Eternity. Dormammu, Baron Mordo and Tony Stark appearance.
Strange Tales #159 1967 Captain America and Origin of Nick Fury 1st appearance of Val.
Strange Tales #179 CGC 9.8 Off-White to White Pages 1st appearance of Pip the Troll. SIGNED BY JIM STARLIN ON 5/17/19
Strange Tales #179 CGC 9.8 White Pages 1st appearance of Pip the Troll.
Sub-Mariner #10 1969 Origin of the Serpent Crown; First appearance of Lemurians; First appearance of Karthon the Quester
Sub-Mariner #35 1971 Namor, Hulk, Silver Surfer battle Avengers; 1st Defenders
Sub-Mariner #9 1969 First appearance of Naga; First appearance of Serpent Crown
Superman Unchained #1 CGC 9.8 White Pages SIGNED BY JIM LEE ON 5/18/19
Superman Unchained #6 Sketch Cover Variant CGC 9.8 White Pages SIGNED BY JIM LEE ON 11/22/15
Tales of Suspense #39 CGC 6.5 Off-White Origin and 1st appearance of Iron Man (Tony Stark). SIGNED BY GENE COLAN ON 12/06/08 & STAN LEE ON 12/18/08
Tales of Suspense #77 CGC 9.2 1st full appearance of Peggy Carter & Ultimo, SIGNED BY STAN LEE & JOHN ROMITA
Tales to Astonish #13 CGC 7.0 SS Signed Stan Lee and Larry Lieber, 1st appearance of Groot.
The Demon #1 CGC 9.8 White Pages (8/72) Origin and 1st appearance of the Demon (Etrigan) and Randu.
The Joker #1 CGC 9.8 White Pages (5/75) 1st Joker in own series.
Uncanny X-Men #109 1978 1ST APPEARANCE OF WEAPON ALPHA (JAMES HUDSON, LATER BECOMES GUARDIAN AND VINDICATOR)
Uncanny X-Men #114 1978 1ST USE OF "UNCANNY" IN THE LOGO
Uncanny X-Men #119 1979 CAMEO OF PROTEUS
Warlock #15 CGC 9.8 White Pages Thanos appearance. Last issue. Story continued in Marvel Team-Up #55